A concise new route to arogenate [L-(8S)-β-(1-carboxy-4-hydroxy-2,5-cyclohexadien-1-yl)alanine diammonium salt]1 in which Michael addition of the anion derived from methyl 1,4-dihydrobenzoate 2 to the dehydroalanine derivative 3 is the key C–C bond-forming step is described.
M. J. Crossley and R. C. Reid, J. Chem. Soc., Chem. Commun., 1994, 2237 DOI: 10.1039/C39940002237
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