Reactivity of oximes and amide oximes towards oxo-vanadium compounds
Abstract
The reactions of salicylaldoxime and salicylamide oxime with [VO(acac)2] yield several unusual compounds, inculding [V3O3(OR)5(OC6H4CHNO)2](R = Me, Et), [VO2{OC6H4CXNOC(Me)NH}](X = H, NH2) and [VO(OR){OC6H4CHN[graphic omitted]HCOMe}] where the tetradentate ligand results from the coupling of acetylacetone with salicylaldimine and salicylaldehyde.