Stereodivergent synthesis of both diastereoisomeric enoates, including vinylogous acids, is achieved in the kinetic resoultion of branched aldehydes and asymmetrization of prochiral cyclic ketone by chiral phosphorus reagents derived from (–)-8-phenylmenthol.
T. Furuta and M. Iwamura, J. Chem. Soc., Chem. Commun., 1994, 2167 DOI: 10.1039/C39940002167
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