Phosphorus cryptands 3–5 are obtained via[2 + 3] cyclocondensations between phosphodiydrazides 1a, b and phosphorus-p,p-dialdehydes 2a, b while another phosphorus cryptand 10 is prepared by treatment of the sodium salt of a phosphodihydrazone 8 with a dihalogenated phosphorus-containing macrocycle 9.
J. Mitjaville, A. Caminade and J. Majoral, J. Chem. Soc., Chem. Commun., 1994, 2161 DOI: 10.1039/C39940002161
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