Rhodium(II) acetate catalysed hydrosilylation of enamides and N-vinylureas leading to 1-(trialkylsilyl)alkylamine derivatives
Abstract
The [Rh2(OAc)4] catalysed hydrosilylation of enamides and N-vinylureas with dimethylphenylsilane proceeds smoothly in a regio- and site-selective manner to give 1-(trialkylsilyl)alkylamine derivatives in good to high yields.