SCHEDULED MAINTENANCE
Reaction of a variety of 1,2-epoxyalkanes with 2.5 equiv. of bulky metal amide—lithium 2,2,6,6-tetramethylpiperidide—affords the corresponding aldehydes exclusively in high yields; this is the first example of base-promoted isomerization of monosubstituted epoxides to aldehydes.
A. Yanagisawa, K. Yasue and H. Yamamoto, J. Chem. Soc., Chem. Commun., 1994, 2103 DOI: 10.1039/C39940002103
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