The new ligand, hydrotris (2H-benz[G]indazol-2-yl)borate, (L) forms octahedral and mixed octahedral [CoL2] and [CoL(L′)][L′= HB(3-neopentylpyrazolyl)]; an unusual complex [MoL(CO)2(η3-CH2CMeCH2)], the structure of which is established by X-ray crystallography shows L acting in a bidentate manner.
A. L. Rheingold, B. S. Haggerty and S. Trofimenko, J. Chem. Soc., Chem. Commun., 1994, 1973 DOI: 10.1039/C39940001973
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