Issue 17, 1994

Serendipitous desymmetrisation during porphyrazine synthesis: an X-ray crystallographic study of 2,3,7,8,12,13,17,18-octakis(dimethylamino)-2-secoporphyrazine-2,3-dione

Abstract

Linstead macrocyclisation of 2,3-bis(dimethylamino)2(Z)-butenedinitrile gives [2,3,7,8,12,13,17,18-octakis(dimethylamino)porphyrazato]magnesium(II) and the title seco-porphyrazine, the structure of which is established by an X-ray crystallographic study.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1943-1944

Serendipitous desymmetrisation during porphyrazine synthesis: an X-ray crystallographic study of 2,3,7,8,12,13,17,18-octakis(dimethylamino)-2-secoporphyrazine-2,3-dione

N. S. Mani, L. S. Beall, A. J. P. White, D. J. Williams, A. G. M. Barrett and B. M. Hoffman, J. Chem. Soc., Chem. Commun., 1994, 1943 DOI: 10.1039/C39940001943

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