Cluster [WRe2(C5Me5)(O)(CO)8(CCPh)]1a possessing a terminal oxo ligand is prepared by treatment of the acetylide cluster [WRe2(C5Me5)(CO)9(CCPh)] with O2 or N2O; hydrogenation of 1a affords three isolable clusters, showing an example of oxo-ligand mediated sequential conversion of acetylide to alkenyl and alkylidene.
Y. Chi, P. Cheng, H. Wu, D. Hwang, P. Su, S. Peng and G. Lee, J. Chem. Soc., Chem. Commun., 1994, 1839 DOI: 10.1039/C39940001839
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