The coordinative addition of dimethyl sulfide to (C5H5)2Rh2(µ-CO)(µ-CF3C2CF3) is followed by an intramolecular transformation to give (C5H5)2Rh2(µ-SCH2Me){µ-C(CF3)CH(CF3)}, and the corresponding reaction with Et2S gives a related complex with a chiral bridging sulfido group SCHMeEt.
M. P. Devery and R. S. Dickson, J. Chem. Soc., Chem. Commun., 1994, 1721 DOI: 10.1039/C39940001721
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