It has been found that the silicoaluminophosphate molecular sieves SAPO-37 and SAPO-5 are very active in pinacol rearrangement, while SAPO-11 and SAPO-34 showed rather low activity most probably due to pore constraints.
F. A. Jabur, V. J. Penchev and C. P. Bezoukhanova, J. Chem. Soc., Chem. Commun., 1994, 1591 DOI: 10.1039/C39940001591
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