The isotopes from DL-[3-13C]-β-aminoisobutyrate and [13C2H3-methyl]thymine are efficiently incorporated into the seven propionate, and to a lesser extent the butyrate, derived methyl groups in monensin-A from Streptomyces cinnamonensis; catabolic pathways from thymine to methylmalonyl-CoA and isobutyryl-CoA are implicated in antibiotic producing Actinomycetes.
D. O'Hagan, S. V. Rogers, K. A. Reynolds and G. R. Duffin, J. Chem. Soc., Chem. Commun., 1994, 1577 DOI: 10.1039/C39940001577
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