Issue 12, 1994

An EPR study of a palladium catalyst using a PBN (N-benzylidene-tert-butylamine N-oxide) spin trap: direct demonstration of hydrogen spillover

Abstract

EPR spectroscopy, in conjunction with spin trapping, is shown to provide a convenient, simple technique for detecting the dissociation of hydrogen on a supported palladium catalyst and leads to a direct demonstration of the occurrence of spillover on to the alumina support.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1407-1408

An EPR study of a palladium catalyst using a PBN (N-benzylidene-tert-butylamine N-oxide) spin trap: direct demonstration of hydrogen spillover

A. F. Carley, H. A. Edwards, B. Mile, M. W. Roberts, C. C. Rowlands, S. D. Jackson and F. E. Hancock, J. Chem. Soc., Chem. Commun., 1994, 1407 DOI: 10.1039/C39940001407

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