Issue 11, 1994

The thermal decomposition of allylic sulfinic acids: a study of a retro-ene transition state

Abstract

The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 1381-1382

The thermal decomposition of allylic sulfinic acids: a study of a retro-ene transition state

S. D. Hiscock, N. S. Isaacs, M. D. King and D. J. Young, J. Chem. Soc., Chem. Commun., 1994, 1381 DOI: 10.1039/C39940001381

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