The thermal desulfination of allylsulfinic acid proceeds with a negative activation volume, solvent independence and a relatively small deuterium isotope effect which, together with the results of a previous stereochemical study, confirm a concerted retro-ene mechanism and suggest a relatively compact, early transition state.
S. D. Hiscock, N. S. Isaacs, M. D. King and D. J. Young, J. Chem. Soc., Chem. Commun., 1994, 1381 DOI: 10.1039/C39940001381
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