Incorporation of elemental phosphorus into hexagonal-packed C60 gives the new phase {(P4)2C60}; characterisation by powder diffraction and multinuclear solid-state NMR studies show the P4 tetrahedra occupy trigonal prismatic sites and confirm the retention of the molecular nature of the P4 guest.
R. E. Douthwaite, M. L. H. Green, S. J. Heyes, M. J. Rosseinsky and J. F. C. Turner, J. Chem. Soc., Chem. Commun., 1994, 1367 DOI: 10.1039/C39940001367
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