meso-Cyclopentane-1,2-diol was differentiated via diasteroselective C–O bond fission of the acetal utilising the anion stabilised by a neighbouring chiral sulfinyl group to provide the chiral alcohol.
N. Maezaki, M. Soejima, M. Takeda, A. Sakamoto, T. Tanaka and C. Iwata, J. Chem. Soc., Chem. Commun., 1994, 1345 DOI: 10.1039/C39940001345
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