Addition of (C5Me5)Ru+ to (C5Me5)2Ru2S4 affords (C5Me5)3Ru3S4+; this cluster displays S-centred reactivity towards a range of electrophiles (H+, SO2, Me+, Et+) to give adducts with solid-state structures containing Ru3(µ3-S2)(µ3-S)(µ-SR) cores.
E. J. Houser, H. Krautscheid, T. B. Rauchfuss and S. R. Wilson, J. Chem. Soc., Chem. Commun., 1994, 1283 DOI: 10.1039/C39940001283
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