The existence of significant σ–σ* interactions involving the C–Si bonding orbital and the C–O antibonding orbital, results in a strong preference for the diaxial conformation for the esters 6a–m.
Y. L. Kuan and J. M. White, J. Chem. Soc., Chem. Commun., 1994, 1195 DOI: 10.1039/C39940001195
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