Reactions of [{Ln(C5Me5)2H}2](Ln = Y, Sm) with [W(C5H5)2H2] afford the σ-bond metathesis products [(C5Me5)2Ln(µ-η1, η5-C5H4)(µ-H)2W(C5H5)], via dehydrocoupling between the Ln–H bond and the C–H (but not the weaker W–H) bond of [W(C5H5)2H2].
N. S. Radu, P. K. Gantzel and T. D. Tilley, J. Chem. Soc., Chem. Commun., 1994, 1175 DOI: 10.1039/C39940001175
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