The first imidazolate-bridged heterobinuclear copper–zinc complex of a unique macrobicyclic ligand (cryptand) was prepared and characterized by X-ray diffraction; the complex-catalysed dismutation of superoxide anion survives in the presence of bovine serum albumin.
J. Pierre, P. Chautemps, S. M. Refaif, C. G. Béguin, A. El-Marzouki, G. Serratrice, P. Rey and J. Laugier, J. Chem. Soc., Chem. Commun., 1994, 1117 DOI: 10.1039/C39940001117
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