Reductive cleavage of the methylphosphoniatriazaadamantane cation by sodium in liquid ammonia affords the new bicyclic ligand (MeP)(CH2)5N2(NMe) whose structure has been determined from crystals of its 1 : 1 complex with AuCl.
B. Assmann, K. Angermaier and H. Schmidbaur, J. Chem. Soc., Chem. Commun., 1994, 941 DOI: 10.1039/C39940000941
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