One-electron oxidation of nitrosyl-iron(II)β-oxoporphyrin complexes, models for haem d1, with silver hexafluoroantimonate yields the corresponding π-cation radicals, characterized by electronic absorption and IR spectroscopies.
S. Ozawa, E. Sakamoto, Y. Watanabe and I. Morishima, J. Chem. Soc., Chem. Commun., 1994, 935 DOI: 10.1039/C39940000935
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