Issue 7, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

The four-electron oxidation of meso-octaethylporphyrinogen via a metal-mediated dealkylation process: formation of [RuL(PhCN)2][H2L = 5,15-dihydro-5,5,10,15,15,20-hexaethylporphyrin]

Umberto Piarulli,   Carlo Floriani,   Angiola Chiesi-Villa  and  Corrado Rizzoli  

Abstract

A four-electron oxidation of meso-octaethylporphyrinogen (H4L′) involving the dealkylation of two meso carbons has been observed in the reaction between [Ru(Cl)2(PhCN)4] and [Li4L′(THF)4] leading to [RuL(PhCN)2] which contains two hemiporphyrin fragments joined by two sp3 carbons, as shown by an X-ray analysis.

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Article information

DOI
https://doi.org/10.1039/C39940000895
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 895-896

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The four-electron oxidation of meso-octaethylporphyrinogen via a metal-mediated dealkylation process: formation of [RuL(PhCN)2][H2L = 5,15-dihydro-5,5,10,15,15,20-hexaethylporphyrin]

U. Piarulli, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Chem. Soc., Chem. Commun., 1994, 895 DOI: 10.1039/C39940000895

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