The titanium tetrachloride mediated addition reaction of 1,8-bis(trimethylsilyl)octa-2,6-diene (BISTRO) with open-chain conjugated enones affords syn-anti-syn-4,7-divinyldecane-1, 10-diones with a very high diastereoselectivity.
H. Pellissier and M. Santelli, J. Chem. Soc., Chem. Commun., 1994, 827 DOI: 10.1039/C39940000827
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