The species Ni2C2S4{S2C2S2C2(CO2Me)2}2, a new type of molecular electronic component, forms in good yield via two oxidation steps from [Ni{S2C2S2C2(CO2Me)2}2]2–; the extended planar structure of the intermediate [Ni2C2S4{S2C2S2(CO2Me)2}2]2– was confirmed crystallographically.
X. Yang, D. D. Doxsee, T. B. Rauchfuss and S. R. Wilson, J. Chem. Soc., Chem. Commun., 1994, 821 DOI: 10.1039/C39940000821
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