One-electron reduction of 1,5-dihydroflavins with e(aq)– yields a three-electron reduced flavin species (FIH2˙–), which protonates with an associated pKa value of 6.1, whereas the reaction of 1,5-dihydroflavins with CO2˙– yields a similar, but not identical flavin species, which may be an adduct radical.
P. F. Heelis and B. J. Parsons, J. Chem. Soc., Chem. Commun., 1994, 793 DOI: 10.1039/C39940000793
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