[MoV(hidpa)2]–[hidpa3=(oxyimino)dipropionate(3–)] has been synthesised and shown to possess the novel, octacoordinated structure identified for Amavadin, the form in which vanadium(IV) is bound in Amanita muscaria mushrooms; [MoV(hidpa)2]– is capable of both a one-electron reduction and a one-electron oxidation.
H. S. Yadav, E. M. Armstrong, R. L. Beddoes, D. Collison and C. D. Garner, J. Chem. Soc., Chem. Commun., 1994, 605 DOI: 10.1039/C39940000605
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