In situ FT-IR spectroscopy has been used to identify for the first time an unusually stable molecular CO2 species at ca. 2337 cm–1 on a polycrystalline silver catalyst; it is proposed that adsorption occurred at silver sites modified by the presence of subsurface oxygen species, which were located in the vicinity of grain boundary defects.
G. J. Millar, J. Seakins, J. B. Metson, G. A. Bowmaker and R. P. Cooney, J. Chem. Soc., Chem. Commun., 1994, 525 DOI: 10.1039/C39940000525
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