Transient absorption methods have been used to measure the reaction kinetics of Os(pp3) with hydrocarbons, following photodissociation of H2 from Os(pp3)H2; the kinetic selectivity per reactivè C–H bond for pentane over cyclohexane exceeds 80 and that for methane over cyclohexane exceeds 520, higher than any observed previously.
R. Osman, D. I. Pattison, R. N. Perutz, C. Bianchini and M. Peruzzini, J. Chem. Soc., Chem. Commun., 1994, 513 DOI: 10.1039/C39940000513
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