Issue 4, 1994

Direct syntheses of 1-phenylphosphetane and 1-phenylphosphirane. Crystal and molecular structures of cyclotrimerisation precursor complexes fac-[Mo(CO)3(PhPCH2CH2CH2)3] and fac-[Mo(CO)3(PhPCH2CH2)3]

Abstract

Dilithium phenylphosphide reacts with 1,3-dichloropropane or 1,2-dichloroethane to give 1-phenylphosphetane or 1-phenylphosphirane, respectively; the free phosphines have been used to prepare the cyclotrimerisation precursor complexes fac-[Mo(CO)3(Ph[graphic omitted]H2)3] and fac-[Mo(CO)3([graphic omitted]H2)3].

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 475-476

Direct syntheses of 1-phenylphosphetane and 1-phenylphosphirane. Crystal and molecular structures of cyclotrimerisation precursor complexes fac-[Mo(CO)3(PhPCH2CH2CH2)3] and fac-[Mo(CO)3(PhPCH2CH2)3]

Y. B. Kang, M. Pabel, A. C. Willis and S. B. Wild, J. Chem. Soc., Chem. Commun., 1994, 475 DOI: 10.1039/C39940000475

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