K[SPPh2NPPh2S] exhibits a ladder-like polymer structure in which the octahedral geometry about the potassium is achieved via K ⋯ aryl electrostatic interactions.
A. M. Z. Slawin, J. Ward, D. J. Williams and J. D. Woollins, J. Chem. Soc., Chem. Commun., 1994, 421 DOI: 10.1039/C39940000421
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