Me3SiOTf (Tf = CF3SO2) is a useful reagent for electrophilic abstraction reactions involving electron-rich complexes RlrLn(R = H, Cl, Me, Ph; L = PMe3, PEt3); direct external attack of Me3Si+ on R is probably involved.
M. Aizenberg and D. Milstein, J. Chem. Soc., Chem. Commun., 1994, 411 DOI: 10.1039/C39940000411
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