1,4 Addition of several alkyl groups using cuprates and radicals on a conformationally biased chiral enone 3 derived from carbohydrate is described, showing essentially identical diastereoselection in anionic and radical processes and a dramatic influence of the alkyl group size on the sense of 1,2-asymmetric induction.
P. Mayon, M. N. Euvrard, N. Moufid and Y. Chapleur, J. Chem. Soc., Chem. Commun., 1994, 399 DOI: 10.1039/C39940000399
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