Transmetallation of tributyl[(4S, 2E)-4-dibenzylaminopent-2-enyl]stannane 7 by tin(IV) bromide generates an allyltin tribromide which reacts with aldehydes to give 5-aminohex-3-enols 8 with effective 1,5-asymmetric induction.
S. J. Stanway and E. J. Thomas, J. Chem. Soc., Chem. Commun., 1994, 285 DOI: 10.1039/C39940000285
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