A new type of catalysis by copper(I) salts in the Barbier-type aldehyde allylation with tin(II) chloride. Short syntheses of (±)-lavandulol and its γ, δ-dihydro derivative
Abstract
Copper(I) halides and cyanide catalyse the Barbier-type aldehyde allylation with allylation with allylic bromides, chlorides or sulfonates and tin(II) chloride enabling the reaction to take place under very mild conditions with high efficiency.
Please wait while we load your content...