In aqueous medium, in the presence of a surfactant agent and of catalytic amounts of ruthenium derivatives, monopersulfate effectively oxidizes α-chlorinated olefins to hydrochloric acid and the appropriate carboxylic acid and/or carbon dioxide, with rates in excess of 100 turnover min–1 at room temperature.
M. Bressan, L. Forti and A. Morvillo, J. Chem. Soc., Chem. Commun., 1994, 253 DOI: 10.1039/C39940000253
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