Issue 2, 1994

A hydrogen-bond bridged layer host: crystal structure of 2-phenylethylammonium tetracyanonickelate(II)-(N,N-dimethylaniline)(1/1)

Abstract

The ammonio group of 2-phenylethylammonium cation links tetracyanonickelate(II) anions at the N atoms of square-planar Ni(CN)4 moieties through hydrogen bonds to form a layer of doubly-CN-bridged one dimensional extensions of [(PhCH2CH2NH3)2Ni(CN)4]n with protrusion of the 2-phenylethyl groups into the interlayer space; these groups act as the spacers to produce the cavities for the guest N,N-dimethylaniline molecules.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 233-234

A hydrogen-bond bridged layer host: crystal structure of 2-phenylethylammonium tetracyanonickelate(II)-(N,N-dimethylaniline)(1/1)

A. Ebina, S. Nishikiori and T. Iwamoto, J. Chem. Soc., Chem. Commun., 1994, 233 DOI: 10.1039/C39940000233

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