The structure of the excited light-emitter in aequorin bioluminescence was assigned not to an amide anion of coelenteramide but to a phenolate anion on the basis of the luminescence of regenerated aequorin and of the fluorescence of regenerated blue fluorescent protein with coelenteramide analogues including N-methyl derivatives.
T. Hirano, I. Mizoguchi, M. Yamaguchi, F. Chen, M. Ohashi, Y. Ohmiya and F. I. Tsuji, J. Chem. Soc., Chem. Commun., 1994, 165 DOI: 10.1039/C39940000165
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