Issue 2, 1994
From the journal:

Journal of the Chemical Society, Chemical Communications

Novel η3-cyclopentenoyl complexes of ruthenium(IV): X-ray structures of Ru(η5-C5H5)(η3-C5H4OBr)Br2 and Ru(η5-C5H5)(η3-C5H5O)Br2

Karl Kirchner,   Kurt Mereiter  and  Roland Schmid  

Abstract

Ru(η5-C5H5)(η4-C5H4O)Br 1 reacts with Br2 to yield the novel η3-allyl complex Ru(η5-C5H5)(η3-C5H4OBr)Br23; treatment of Ru(η5-C5H5)(η4-C8H12)Br 5 with 3-bromo-4-cyclopentene-1-one gives the parent cyclopentenoyl complex Ru(η5-C5H5)(η3-C5H5O)Br26, which in the presence of NEt3 is readily converted to the cyclopentadienone complex 1; X-ray structures of 3 and 6 are presented.

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Article information

DOI
https://doi.org/10.1039/C39940000161
Article type
Paper

J. Chem. Soc., Chem. Commun., 1994, 161-162

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Novel η3-cyclopentenoyl complexes of ruthenium(IV): X-ray structures of Ru(η5-C5H5)(η3-C5H4OBr)Br2 and Ru(η5-C5H5)(η3-C5H5O)Br2

K. Kirchner, K. Mereiter and R. Schmid, J. Chem. Soc., Chem. Commun., 1994, 161 DOI: 10.1039/C39940000161

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