ESR spectroscopic evidence is given to suggest that NO2 initiates radical formation instead of the previously assumed ring-closure mechanism in the reaction of nitric oxide with 2,3-dimethyl-1,3-butadiene and 2,5-dimethyl-2,4-hexadiene.
A. Rockenbauer and L. Korecz, J. Chem. Soc., Chem. Commun., 1994, 145 DOI: 10.1039/C39940000145
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