Issue 12, 1993

Triphenylstannyl anions and related moieties as leaving groups in elimination reactions

Abstract

Reactions of strong bases with β-triphenylstannyl substituted propionitriles give high yields of alkenes under mild conditions through, probably, an E1cB mechanism; under the same reaction conditions, β-trialkylstannyl substituted propionitriles give substantially lower yields of elimination products.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1993, 2323-2324

Triphenylstannyl anions and related moieties as leaving groups in elimination reactions

J. C. Podestá, A. B. Chopa, A. D. Ayala and L. C. Koll, J. Chem. Soc., Perkin Trans. 2, 1993, 2323 DOI: 10.1039/P29930002323

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