Issue 11, 1993

Formation of cyclopropylsulfones from 1-arylsulfonyl-2-chloromethylprop-2-enes

Abstract

Methylenecyclopropyl sulfones are not formed when the title chlorosulfones are treated with methanolic methoxide; instead 1-arylsulfonyl-2-methoxy-2-methylcyclopropanes are formed by an addition–cyclisation sequence involving intramolecular displacement of chloride and not methoxide as suggested by other workers.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1993, 2163-2164

Formation of cyclopropylsulfones from 1-arylsulfonyl-2-chloromethylprop-2-enes

S. M. Jeffery and C. J. M. Stirling, J. Chem. Soc., Perkin Trans. 2, 1993, 2163 DOI: 10.1039/P29930002163

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