The acetolysis of 2,2-dimethyl-1-(p-methoxyphenyl)propyl chloride has been found to be the first example of the SN2C+-type solvolysis under typical SN1 solvolysis reaction conditions, on the basis of its kinetic, stereochemical, and isotopic features.
T. Kinoshita, H. Ueda and K. Takeuchi, J. Chem. Soc., Perkin Trans. 2, 1993, 603 DOI: 10.1039/P29930000603
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