The first total synthesis of (±)-isosarcophytol-A, a marine natural cembronoid, has been achieved in a seven-step synthesis starting from E,E-farnesyl acetate. A titanium-induced dicarbonyl macrocyclization is the key step.
Y. Li, W. Li and Y. Li, J. Chem. Soc., Perkin Trans. 1, 1993, 2953 DOI: 10.1039/P19930002953
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