The calix[4]arene conformation can be immobilized by stapling the upper rim with catechol, resorcinol or, salicylic acid: in certain cases novel molecular asymmetry is generated.
A. Ikeda and S. Shinkai, J. Chem. Soc., Perkin Trans. 1, 1993, 2671 DOI: 10.1039/P19930002671
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