Issue 14, 1993

First total synthesis of (±)-peridinin, (±)-pyrrhoxanthin and the optically active peridinin

Abstract

The first total synthesis of peridinin 1 and pyrrhoxanthin 2 has been accomplished via the reaction of the C15-epoxy formyl ester 21 with the C22-allenic sulfone 28 or the C22-acetylenic sulfone 39. A synthesis of optically active peridinin has also been achieved starting from the (4R,6R)-hydroxy ketone 5.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1993, 1599-1610

First total synthesis of (±)-peridinin, (±)-pyrrhoxanthin and the optically active peridinin

Y. Yamano and M. Ito, J. Chem. Soc., Perkin Trans. 1, 1993, 1599 DOI: 10.1039/P19930001599

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