2-[Bis(trimethylsilyl)amido]-1,3.2-diazaphospholidine, [N,N′-(CH2NMe)2]P[N(SiMe3)2]1, has been synthesised from [N,N′-(CH2NMe)2]PCl and Li[N(SiMe3)2]. The activity of 1 as a phosphonylating agent is demonstrated by its ability to undergo the Abramov reaction with aldehydes.
V. Sum and T. P. Kee, J. Chem. Soc., Perkin Trans. 1, 1993, 1369 DOI: 10.1039/P19930001369
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