Issue 5, 1993

Enzymatic regioselective alkoxycarbonylation of hexoses and pentoses with carbonate oxime esters

Abstract

Hexoses and pentoses have been alkoxycarbonylated with different preparations of Candida antarctica lipase, using acetone O-(alkoxycarbonyl)oximes. A wide variety of alkoxycarbonyl groups are introduced in an easy manner at the primary hydroxy group of several pentoses and hexoses. Of especial importance are the introduction of allyloxy- and benzyloxy-carbonyl groups.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1993, 589-592

Enzymatic regioselective alkoxycarbonylation of hexoses and pentoses with carbonate oxime esters

R. Pulido and V. Gotor, J. Chem. Soc., Perkin Trans. 1, 1993, 589 DOI: 10.1039/P19930000589

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