A series of α′-diphenylphosphinoyl enones has been prepared and their s-cis or s-trans conformations correlated with 1H NMR and IR spectra and an X-ray crystal structure of the title compound. The effect of chelation to cerium(III) is correlated with the regio- and stereo-selectivity of reductions under the Luche conditions.
M. J. Doyle, D. Hall, P. R. Raithby, N. Skelton and S. Warren, J. Chem. Soc., Perkin Trans. 1, 1993, 517 DOI: 10.1039/P19930000517
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