The addition of diethyl bromodifluoromethylphosphonate 1 to various alkenes 2 initiated by cobaloxime(III)/Zn bimetal redox system gives 1:1 Michael-type adducts 3 in moderate to good yields. A radical mechanism is proposed.
C. Hu and J. Chen, J. Chem. Soc., Perkin Trans. 1, 1993, 327 DOI: 10.1039/P19930000327
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